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then negotiates with the site schedulers that manage individual resources We coin the term Computational Resource Broker (CRB) to denote this entity In an Internet-scale distributed computing system, we can imagine a network of such brokers In the I-WAY, one was suf cient 451 Scheduler design The practical realization of the CRB concept requires the development of fairly general user-to-CRB and CRB-to-resource scheduler protocols Time constraints in the I-WAY project limited what we could achieve in each area On the user-to-CRB side, we allowed users to request access only to prede ned disjoint subsets of I-WAY computers called virtual machines; on the CRB-to-resource scheduler side, we required sites to turn over scheduling control of speci ed resources to the I-WAY scheduler, which would then use the resources to construct virtual machines.

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Palladium complexes exhibit even higher catalytic actIvIty and produce branched acids preferentially.132,133 The selectivity, however, can be shifted to the formation of linear acids by increasing the phosphine concentration. 134 Temperature, catalyst concentration, and solvent may also affect the isomer ratio. 135 Marked increase in selectivity was achieved by the addition of Group IVB metal halides to palladium 136 and platinum complexes.137 Linear acids may be prepared with selectivities up to 99% in this way. The formic acid-Pd(OAch-l,4-bis(diphenylphosphino)butane system has been found to exhibit similar regioselectivities. 138 Significant enhancements of catalytic activity of palladium complexes in carbomethoxylation by use of perfluoroalkanesulfonic acid resin cocatalysts was reported. 139,140 The formation of branched acids from 1- and 2-alkenes in a palladium-catalyzed carboxylation was found to be completely regioselective, when the reaction was carried out in the presence of CuCI 2, oxygen, and limited amounts of water and hydrochloric acid, under remarkably mild conditions: 141

Descartes to Mersenne dated March 1, 1638. Translated by Eric Simon. Ibid., p. 170. See, e.g., Aczel, 1996, and Singh, 1997. Fermat to Mersenne, December 1637; Fermat Oeuvres, vol. 2, p. 116. Translated by Daniel Curtin. Fermat to Mersenne, February 1638. Fermat Oeuvres, vol. 2, pp. 132, 133. Translated by Daniel Curtin. Fermat to Mersenne, April 20, 1638. Fermat Oeuvres, vol. 2, pp. 136, 137. Translated by Daniel Curtin. Descartes to Mersenne,June 29, 1638; in Mahoney, 1994, p. 192. Translation in Mahoney, 1994, p. 58. Bell, 1937, p. 64. Ball, 1960, p. 293. Mahone~ 1994,p.23. Barner, 2001, p. 15. Barner, 2001, pp. 15-16. See, e.g., Scott, 1976, p. 85; Mahoney, 1994, pp. 27-28, 181; and Coolidge, 1940, p. 119. Gaukroger points out that Descartes' early notation was clumsy and derived from that of Clavius, and that this "indicates that he had not read Vihe before developing his own account." (Personal communication,January 15, 2004 ) Mahone~ 1994,p. 181. Ibid., p. 388. Ibid. From translatlons by both]. D. Nicholson, an independent scholar, and Daniel]. Curtin, a professor of mathematics at Northern Kentucky University. Fermat to Clerselier, March 10, 1658. Translated and elucidation by James Nicholson. Horace, the Odes ami EpQdes, with an English translation by Charles E. Bennett (New York: The Macmillan Company, 1914). Bennett was a famous translator of Latin works. Sabra, 1981, p. 130. Vi = velocity of the incident light, and v, = velocity of the refracted light. Sabra, 1981, p. 149. Sabra, 1981,p. 135. Ad Locus PIanos et Solufos Isagoge (Introduction to Loci Consisting of Straight Lines and Curves of the Second Degree). Letter to Marin Cureau de la Chambre,January 1, 1662. Translated by Eric Simon.

In effect, our simple CRB obtained access to a block of resources, which it then distributed to its users The scheduler that was de ned to meet these requirements provided management functions that allowed administrators to con gure dedicated resources into virtual machines, obtain status information, and so forth and user functions that allowed users to list available virtual machines and to determine status, list queued requests, or request time on a particular virtual machine The scheduler implementation was structured in terms of a single central scheduler and multiple local scheduler daemons The central scheduler daemon maintained the queues and tables representing the state of the different virtual machines and was responsible for allocating time on these machines on a rst-come, rst-served basis It also maintained state information on the AFS le system, so as to provide some fault tolerance in the case of daemon failures.